Updated with 1.0.18 events.
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Prostitution

Go after 8pm to the male npc house.

The only ones not included (Yet?) are :
-Gus
-Krobus
-Dwarf
-Wizard
-Pierre
-Marlon?
-George

Note: You Cant prostitue with your husband. 
So those events wont play if you go to their house at night when married to them.

-New on "1_0_16" "Quicksex!"  The action ends in 2 or 3 seconds..  -20 friendship points (a heart is 250 points)
You still get paid and the cum item.  (just 4 npcs have this option for now)
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Sex with your Husband   *Compatible with Multyple spouses.

All the vanilla Bachelors But Krobus. (Yes, you can marry Krobus)

There is a 30% chance per night when you enter your house after 8pm
that your husband ask for sex. (This increase happynes value <3)

-What is the difference of prostitution and this? :
-Prostitution yields money, a cum item and a small friendship increase
-Husband sex yields X2 cum items, medium friendship increase

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FratValley Events Guide

Professor:
  1 Heart - Professor Room
  2 Hearts - Beach
  3 Hearts - Professor's Room
  4 Hearts - Professor's Room
  5 Hearts - Professor's Room
  6 Hearts - Professor's Room
  7 Hearts - Professor's Room

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Kent as your servant

-Special event on Year 2 on The Professor room, to turn Kent into the farmers servant.

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Denver:
  0 Hearts - FratValley Hub
  1 Heart - FratValley Hub
  2 Hearts - Town
  3 Hearts - Blacksmith
  4 Hearts - Pierre's Shop
  5 Hearts - Forest
  6 Hearts - FratValley Hub
  7 Hearts - Town
  8 Hearts - Brandon's Room
  9 Hearts - Mountain   / Robins house, Mines area
  10 Hearts - Professor's Room

New! - You can now find Denver on the Mens Locker room On the spa, after 12pm (For prostitution)

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Brandon:
  0 Hearts - Brandon's Room
  1 Heart - Town
  2 Hearts - Town
  3 Hearts - Bus Stop
  4 Hearts - Beach
  5 Hearts - Town
  6 Hearts - Moutain / Robins house, Mines area
  7 Hearts - Beach
  8 Hearts - Bus Stop
  9 Hearts - Brandon's Room

-On a Wed, Thu or Sat, Brandon will stop next to the Saloon, if u talk to him he'll ask if u'll go with him to the beach and you can answer yes or no. if you awnser"yes", then an event will happen on "the Beach". If u answer no, nothing will happen (Repetable)
  
-Every day, if u go to Brandon's Room after 8pm, He will think you are breaking in, and will teach you a lesson. (Yields x2cum)

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Trevor:
  On a friday, after 8pm, go met Trevor at his room (To the east of the TV on the FratValley Hub)
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Kent as a Servant : (Triggered in year 2 in the Professor's Office)

Go to Kents house after owning him on the Professors office event :
Then you will be asked what to do with him for that day

You can repeat this event every day!
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Dominus:
  If you have his content enabled (On the Devious Valley Options menu, Default : true)

Warning! : This choice* is permanent, and it contains high dominant BDSM themes - Aimed for the farmer as a Sub, making the farmer life a bit more devious and hard. 
(* You can always choose to say no in dialogue. The question wont be asked again for that playthrough tho.)

-You can visit him into his shack close to Marnies house, to the east close to the Town entrance.
He will offer you a contract

Accepting it will give you a series of quests, rules and orders that will aply across the valley.
The more you acomplish the more quests and new rules you get, so you can become the perfect servant.

-Quests include (but not limited to)
+Serving older dudes in town
+Paying your master money
+You master whoring you for cheap money
+Pissplay
etc.

All of that on specific days.
(All the quest are guided, there will be pinned notes on Dominus in form of "Stands with scrolls" after you accept the new orders.)


Complete quests to get more favor points, so you can buy new rule tokens (Those will trigger an event on Dominus Shack, so he teach you the new ways)

-After you accept to take part as Dominus servant. You can go to his office after 10pm any night for a free whipping session.


-And more stuff to come!

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Misc

Alastor: 
Minievent on the mountains. East to the Carpenter shop, there is a cave....